To validate a field having a non-duplicate value edit your field then navigate to Integrations > CB Query Field > Query Validation and configure the following.
Query Validation: Enabled
Query:
Code:
SELECT `id` FROM `#__comprofiler` WHERE `id` != '[user_id]' `FIELD_NAME_HERE` != '[value]'
Validate On: Empty Results
Error Message: You are already registered.
Ajax Validation: Enabled
Replace FIELD_NAME_HERE with the name of your field. In your case replace it with cb_ama.